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patrónite
Patronite is the vanadium sulfide mineral with formula VS4. The material is usually described as V4+(S22-)2. Structurally, it is a "linear-chain" compound with alternating bonding and nonbonding contacts between the vanadium centers. The vanadium is octa-coordinated, which is an uncommon geometry for this metal.
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- John Wiley
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(United States)