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electron paramagnetic resonance (epr) spectroscopy

The study of the resonant response to microwave- or radio-frequency radiation of paramagnetic materials placed in a magnetic field. It is sometimes referred to as electron spin resonance (ESR). Paramagnetic substances normally have an odd number of electrons or unpaired electrons, but sometimes electron paramagnetic resonance (EPR) is observed for ions or biradicals with an even number of electrons. EPR spectra are normally presented as plots of the first derivative of the energy absorbed from an oscillating magnetic field at a fixed microwave frequency versus the magnetic field strength. The dispersion may also be detected.

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