首页 >  Term: extended x-ray absorption fine structure (EXAFS)
extended x-ray absorption fine structure (EXAFS)

The structured absorption on the high-energy side of an x-ray absorption edge. The absorption edges for an element are abrupt increases in x-ray absorption that occur when the energy of the incident x-ray matches the binding energy of a core electron (typically a 1s or a 2p electron). For x-ray energies above the edge energy, a core electron is ejected from the atom. The ejected core electron can be thought of as a spherical wave propagating outward from the absorbing atom. The photoelectron wavelength is determined by its kinetic energy, which is in turn determined by the difference between the incident x-ray energy and the core-electron binding energy. As the x-ray energy increases, the kinetic energy of the photoelectron increases, and thus its wavelength decreases.

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