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kernite

A hydrated borate mineral with chemical composition Na2B4O6(OH)2·3H2O. It is monoclinic with symmetry 2/m. It occurs only very rarely in crystals but is found most commonly in coarse, cleavable masses (see illus.) and aggregates. It has two perfect cleavages, (001) and (100), at about 71° to each other, which together produce cleavage fragments that are elongated parallel to the b crystallographic axis. It is colorless to white; colorless and transparent specimens tend to become chalky white on exposure to air with the formation of tincalconite, Na2B4O5(OH)4·3H2O. The structure of kernite, with space group P 2/a, contains infinite chains of composition (B4O6(OH)2)2- which run parallel to the b crystallographic axis. The chains are linked to each other by bonding to Na+ and by hydroxyl-oxygen bonds.

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