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selection rules (physics)

General rules concerning the transitions which may occur between the states of a quantum-mechanical physical system. They derive in almost all cases from the symmetry properties of the states and of the interaction which gives rise to the transitions. The system may have a classical (nonquantum) counterpart, and in this case the selection rules may often be related to the classical conserved quantities. A first use of selection rules is in determining the symmetry classes of the states, but in a great variety of ways they may yield other information about the system and the conservation laws.

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